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- W2014203556 startingPage "1867" @default.
- W2014203556 abstract "The rates of amine hydrogen isotopic exchange in the [Co(O)2(N)4]+ complex ions, where (O)2 represents carbonate, oxalate, or malonate ions, and (N)4, tetraammine, bis(ethylenediamine), or bis(trimethylenediamine), were measured in D2O at 35 °C by the PMR technique. It was found that: (1) the rates for trans (to oxygen) amines are faster than those for cis amines; (2) the rates, especially for trans amines, in the carbonato complexes are slower than those in the oxalato and malonato analogs, and (3) the difference between the rates for cis and trans amines is smaller in the bis(diamine) complexes than in the tetraammine complexes. These results are discussed in terms of the influence of the chelate geometry in the complex on the exchange reaction." @default.
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- W2014203556 date "1976-07-01" @default.
- W2014203556 modified "2023-09-26" @default.
- W2014203556 title "Proton Magnetic Resonance Spectra of Metal Ammine Complexes. VIII. Hydrogen Isotopic Exchange in the [Co(O)<sub>2</sub>(N)<sub>4</sub>]<sup>+</sup>Complex Ions" @default.
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- W2014203556 doi "https://doi.org/10.1246/bcsj.49.1867" @default.
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