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- W2014204443 abstract "Oxidation behavior of a TiN0.74 coupon was studied in a temperature range 1100 to 1300 K in a flow of purified oxygen at atmospheric pressure. The thermogravimetry showed two-stage parabolic laws with the rate constant of the first stage, Kp1, being slightly smaller than that of the second stage, Kp2. They are expressed in the following equations in kg2·m−4·s−1, with activation energies in J·mol−1.Kp1=79exp(−183000⁄RT)Kp2=33.6exp(−171000⁄RT)During the initial periods the oxide scale consists of a dense outer rutile layer and an inner rutile layer containing micropores randomly distributed. However, as the oxidation proceeds, a multi-layered structure develops in the inner layer by the repeated evolution of micropores aligned in lines almost parallel to the substrate. After a very long oxidation period, however, the layered structure becomes very vague because of sintering of the oxide. The growth of the inner layer showed a transition from parabolic to linear manner. These observations are explained in terms of the change in the scale structure which was attributable to the saturation of the substrate with nitrogen liberated by the consumption of titanium." @default.
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- W2014204443 date "1989-01-01" @default.
- W2014204443 modified "2023-09-27" @default.
- W2014204443 title "Oxidation Behavior of TiN<SUB>0.74</SUB> at High Temperatures" @default.
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- W2014204443 doi "https://doi.org/10.2320/matertrans1989.30.765" @default.
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