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- W2014208020 abstract "The catalytic properties of titanium pyrophosphate in the oxidative dehydrogenation of isobutane to isobutylene were investigated in the 400 ? 550 ?C temperature range. Asignificant change of the product distribution and of the apparent activation energy of the reaction was observed at about 490 ?C. This phenomenon, already observed in the oxidative dehydrogenation of n-butane, has been interpreted by the existence of two reaction mechanisms depending upon the reaction temperature. Comparison with the n-butane reaction allowed different activation pathways for the activation of alkanes to be proposed. The catalytic properties of TiP2O7 in the oxidative dehydrogenation of isobutane was also compared to those obtained previously with several other pyrophosphates and TiP2O7 was found to be less active and selective for this reaction." @default.
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- W2014208020 date "2005-01-01" @default.
- W2014208020 modified "2023-10-18" @default.
- W2014208020 title "Oxidative dehydrogenation of isobutane over titanium pyrophosphate catalyst" @default.
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- W2014208020 doi "https://doi.org/10.2298/jsc0506791m" @default.
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