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- W2014209825 abstract "The effect of selective product removal in the equilibrium limited metathesis of propene was studied in a membrane enclosed catalytic reactor. Propene is converted into ethene and 2-butene, the latter component is formed in cis and trans geometry. The silicalite-1 membrane used in this study is able to separate trans-2-butene from propene (sel. ∼ 5) and of cis-2-butene (sel. ∼ 1.6). Under optimal operating conditions of the membrane enclosed catalytic reactor, the propene conversion was 13 % higher than the thermodynamic equilibrium conversion. A 34% increase in the ratio in which trans-2-butene and cis-2-butene are formed was observed. The performance of the membrane reactor was clearly a balance between the rates of reactant loss and product removal was clearly shown." @default.
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- W2014209825 date "1999-05-01" @default.
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- W2014209825 title "Application of a zeolite membrane reactor in the metathesis of propene" @default.
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- W2014209825 doi "https://doi.org/10.1016/s0009-2509(99)00045-7" @default.
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