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• W2014219616 abstract "Abstract The mechanism of methylpyrazine ammoxidation on a vanadia–titania catalyst has been studied by in situ FTIR spectroscopy. The structure of surface intermediates has been identified and the sequence of their transformation in the temperature range of 150–230 °C has been ascertained. The interaction of methylpyrazine with catalyst surface includes a consecutive transformation of coordinatively bound methylpyrazine into oxygenated surface compounds, viz., an aldehyde-like complex and an asymmetrical carboxylate. The main reaction product, amidopyrazine, is formed through the interaction of the surface oxyintermediates with adsorbed ammonia species." @default.
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• W2014219616 date "2007-05-01" @default.
• W2014219616 modified "2023-09-24" @default.
• W2014219616 title "Investigation of the reaction mechanism of methylpyrazine ammoxidation on vanadia–titania catalyst by FTIR in situ" @default.
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• W2014219616 doi "https://doi.org/10.1016/j.molcata.2007.01.021" @default.
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