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• W2014232158 endingPage "423" @default.
• W2014232158 startingPage "391" @default.
• W2014232158 abstract "Definitive 1H, 31P and 195Pt NMR data are reported for the complexes [PtX2(dppm)] (X = Cl, Br or I; dppm = Ph2PCH2PPh2), [Pt2X2(μ-dppm)2], [Pt2X2(μ-H)(μ-dppm)2]+, [Pt2H2(μ-H)(μ-dppm)2]+, [Pt2Cl2(μ-Y)(μ-dppm)2] (Y = CH2. S or SO2), [Pt2Me2(μ-Cl)(μ-dppm)2]+ and [Pt2Me3(μ-dppm)2]+. The complexes [Pt2X2(μ-H)(μ-dppm)2]+ (X = Br or I) are reported for the first time, and the evidence is presented that [Pt2H2Cl(μ-ddpm)2]+ has a ‘T’-frame structure (involving a donor-acceptor metal-metal bond) rather than an ‘A’-frame structure. Early preparative routes to [Pt2X2)μ-dppm)2] (X = Cl, Br or I) were shown to give complexes contaminated with small amounts of [Pt2X2(μ-H)(μ-dppm)2]X, and rapid intermolecular proton transfer between [Pt2X2(μ-dppm)2] and [Pt2X2(μ-H)(μ-dppm)2]+ was observed: for X = Cl, ΔG≠ is 44.1 kJ mol−1. The merits of 195Pt NMR spectroscopy for studying platinum dimers are discussed, and a correlation between 1J(PtPt) and r(PtPt) was observed." @default.
• W2014232158 created "2016-06-24" @default.
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• W2014232158 date "1986-05-01" @default.
• W2014232158 modified "2023-09-24" @default.
• W2014232158 title "BIS-μ-[BIS(Diphenylphosphino)Methane]Dihalodiplatinum-(Pt-Pt) and its hydrido ‘A’-frame derivatives revisited" @default.
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• W2014232158 doi "https://doi.org/10.1016/0022-328x(86)80157-7" @default.
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