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- W2014234400 abstract "A first-order theory of compositional segregation at solid/liquid interfaces, based on a pair-bonded, lattice-liquid interfacial model, has been applied to predict the effect of segregation on the orientation dependence of the interfacial free energy in binary metallic systems. The results show that the sharpness of the cusps in the gamma plot is reduced due to preferential segregation at layer edges as compared to layer faces, and cusps may be eliminated under certain conditions. The reduction in cusp sharpness is the greatest when the composition difference of the solid and liquid phases is large and the solutions are appreciably non-ideal. The relative reduction of sharpness due to segregation is less pronounced for cusps which are sharper in the unsegregated condition, so segregation tends to smooth the form of the gamma plot. Graphical results are presented for calculation of segregational anisotropy effects in general systems." @default.
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- W2014234400 title "Orientation dependence of the solid/liquid interfacial free energy in binary systems" @default.
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- W2014234400 doi "https://doi.org/10.1016/0039-6028(76)90192-8" @default.
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