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- W2014238727 abstract "The crystal structures of the hexagonal compounds Cs4CoCr4F18 (a = 720.3, c = 1076.1 pm) and Cs4Cr5F18,24 (a = 720.0, c = 1067.9 pm), both crystallizing in space group P3̄m1, Z = 1, have been determined (Rg = 0.041 and 0.045, respectively). They exhibit a new triple layer arrangement of octahedra, which has the composition M5F18 and derives from the RbNiCrF6-type pyrochlore structure. The overall average distances are M-F = 192.9 and 192.0 pm for the Co(II) and the Cr(II) compound, respectively, the smaller value of the latter being mainly due to the higher Cr(III) portion in it. The compensating anion excess is located and its influence discussed, as well as the evidence on the distribution of M(II) and M(III) ions on the lattice sites, including some hints on the presence of a Jahn-Teller distortion in the Cr(II) compound." @default.
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- W2014238727 date "1983-10-01" @default.
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- W2014238727 title "Structures of cesium containing fluorides, VI: The pyrochlore-related layer structures of Cs4CoCr4F18 and Cs4Cr5F18+x" @default.
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- W2014238727 doi "https://doi.org/10.1016/s0022-4596(83)80013-9" @default.
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