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- W2014248853 abstract "Subpicosecond time-resolved fluorescence of trans-4-dimethylamino-4'-cyanostilbene (DCS) is used to measure solvation dynamics in the gas-expanded liquid (GXL) system CH(3)CN + CO(2) at 25 degrees C along the liquid-vapor coexistence curve. These measurements are supplemented by measurements of the steady-state solvatochromism of DCS and of its rotation and isomerization times. Molecular dynamics computer simulations and a semiempirical spectral model that reproduces the observed solvatochromism in this system are used to interpret the experimental results. Simulations indicate that at compositions of x(CO2) > 0.5, the cybotactic region surrounding DCS is enriched in CH(3)CN molecules, and the extent of this enrichment is greater in S(1) than that in S(0). Solvation dynamics are dominated by the CH(3)CN component. These dynamics are biphasic, consisting of a subpicosecond inertial component, followed by a slower picosecond component, related to the redistribution of CH(3)CN molecules between the cybotactic region and the bulk solvent." @default.
- W2014248853 created "2016-06-24" @default.
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- W2014248853 date "2008-11-01" @default.
- W2014248853 modified "2023-09-27" @default.
- W2014248853 title "Solvation and Solvatochromism in CO<sub>2</sub>-Expanded Liquids. 3. The Dynamics of Nonspecific Preferential Solvation" @default.
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- W2014248853 doi "https://doi.org/10.1021/jp805620q" @default.
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