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- W2014263399 abstract "Abstract The standard association constants of the ion pair [MgSO 4 ] 0 , K ass , in the {0.06455 ethanol + 0.93545 water} were determined from precise e.m.f. measurements of cell (I) without liquid junction: (I) Pt , H 2 ( 101.325 kPa ) | HCl ( m 1 ) , MgSO 4 ( m 2 ) , ( 0.06455 ethanol + 0.93545 water ) | AgCl - Ag , where m i means molality of species i . The dependence of p K ass on temperature T is expressed by the empirical equations: p K ass = a 1 + a 2 ( K / DT ). The other thermodynamic functions of the association process were also calculated and showed that the driving force for the formation of the ion pair is the entropy of association." @default.
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- W2014263399 date "2006-01-01" @default.
- W2014263399 modified "2023-09-23" @default.
- W2014263399 title "Thermodynamics of ion pair in mixed solvents: II. The system (HCl+MgSO4) in {0.06455C2H5OH+0.93545H2O}" @default.
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- W2014263399 doi "https://doi.org/10.1016/j.jct.2004.12.013" @default.
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