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- W2014263741 abstract "The major reactions of aryl substituted N-t-butylbenzamides upon electron-impact involve direct cleavage of a methyl radical, the loss of a butene molecule with the transfer of one hydrogen, or the loss of a butenyl radical with the transfer of two hydrogens. The last of these processes parallels the mass spectral behavior of aliphatic amides. Substituent effects indicate that electron-withdrawing groups on the aromatic ring enhance the two hydrogen transfer process, while electron-donating groups enhance the single hydrogen transfer process. Ion abundances, ionization potentials and appearance potentials are discussed with respect to correlation with σ+ values." @default.
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- W2014263741 title "Mass spectra of aryl substitutedN-t- butylbenzamides: Substituent effects on unimolecular ion decomposition" @default.
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- W2014263741 doi "https://doi.org/10.1002/oms.1210090609" @default.
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