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- W2014281625 abstract "The two isomeric NHD-, the ND2-, the 5-D- and 5-D,ND2-isotopomers of furfurylamine have been studied by microwave spectroscopy, thus extending a previous study. Substitution coordinates have been obtained for the two hydrogen atoms of the amino group and for 5-H in the principal axis system of the parent furfurylamine as well as in the corresponding system of the ND2-isotopomer. The problem of deciding whether the orientation of the amino group relative to the furan oxygen corresponds to a hydrogen bonded situation or not, has been solved by comparison of the substitution coordinates of 5-H in the two principal axis systems and it has been confirmed that the molecule is actually hydrogen bonded, but with a very weak hydrogen bond. The conformation of furfurylamine is staggered with respect to both the C(2)C(6) and C(6)N(7) bonds. A second conformer with an inverted hydrogen at N is expected but has not been found." @default.
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- W2014281625 date "1990-06-01" @default.
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- W2014281625 title "Conformation of furfurylamine studied by microwave spectra of five deuterated isotopomers of furfurylamine" @default.
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- W2014281625 doi "https://doi.org/10.1016/0022-2860(90)80459-w" @default.
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