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- W2014282452 abstract "Mesoporous-like heterogeneous catalyst, consisting of ultrasmall (<5 nm) amorphous Fe2O3 and nanocrystalline γ-Fe2O3 possessing surface area of 440 m2 g−1 and reaching an enormous rate constant of 70 × 10−3 min−1 in hydrogen peroxide decomposition at room temperature, pH of 6.3–6.5 and the catalyst concentration of 1 g L−1 was easily prepared by a one-step quasi-isothermal decomposition (an isothermal decomposition accompanied with a controlled time-limited exotherm) of iron(III) oxalate in air. The non-equilibrium temperature conditions proceeding at the very beginning of the oxalate decomposition proved to be the key factor responsible for the formation of highly efficient combination of nanocrystalline character, large surface area and mesoporous-like nature of the catalyst. The material and catalytic properties of the as-prepared catalyst are discussed and compared to those obtained for our iron(III) oxide-based catalyst (26 × 10−3 min−1) prepared earlier by a slow, purely isothermal decomposition of iron(II) oxalate." @default.
- W2014282452 created "2016-06-24" @default.
- W2014282452 creator A5000471912 @default.
- W2014282452 creator A5074315922 @default.
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- W2014282452 date "2010-01-01" @default.
- W2014282452 modified "2023-10-18" @default.
- W2014282452 title "Quasi-isothermal decomposition: a way to nanocrystalline mesoporous-like Fe2O3 catalyst for rapid heterogeneous decomposition of hydrogen peroxide" @default.
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- W2014282452 doi "https://doi.org/10.1039/c000632g" @default.
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