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• W2014286257 startingPage "1123" @default.
• W2014286257 abstract "Five new copper(II) complexes [Cu(dbsf)(H2O)]n · 0.5n(i-C3H7OH) (1), [Cu(dbsf)(4,4′-bpy)0.5]n · nH2O (2), [Cu(dbsf)(2,2′-bpy)(H2O)]2 · (n-C3H7OH) · 0.5H2O (3), [Cu(dbsf)(phen)(H2O)]2 · 1.5H2O (4) and [Cu(dbsf)(2,2′-bpy)(H2O)]n · n(i-C3H7OH) (5) (H2dbsf = 4,4′-dicarboxybiphenyl sulfone, 4,4′-bpy = 4,4′-bipyridine, 2,2′-bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline, i-C3H7OH = isopropanol, n-C3H7OH = n-propanol) have been synthesized under hydro/solvothermal conditions. All of the complexes are assembled from V-shaped building blocks, [Cu(dbsf)]. Complex 1 is composed of 1D double-chains. In complex 2, dbsf2− ligands and 4,4′-bpy ligands connect Cu(II) ions into catenane-like 2D layers. These catenane-like 2D layers stack in an ABAB fashion to form a 3D supramolecular network. Complexes 3 and 4 are 0D dimers, in which two [Cu(dbsf)] units encircle to form dimetal macrocyclic molecules. However, in complex 5, the V-shaped building blocks [Cu(dbsf)] are joined head-to-tail, resulting in the formation of infinite tooth-like chains. The different structures of complexes 3 and 5 may be attributed to the different solvent molecules included." @default.
• W2014286257 created "2016-06-24" @default.
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• W2014286257 date "2007-03-01" @default.
• W2014286257 modified "2023-09-23" @default.
• W2014286257 title "Assembly and structures of five new Cu(II) complexes based on the V-shaped building block [Cu(dbsf)]" @default.
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• W2014286257 doi "https://doi.org/10.1016/j.poly.2006.10.007" @default.
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