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- W2014286522 abstract "The phase NiZn3.r has an orthorhombic end-centred cell with the content 2(34Ni+104Zn) and lattice constants a1 = 33.326 Å, a2 = 8.869 Å and a3 = 12.499 Å; the structure is closely related to the γ-brass type. In contrast with the W-type substructure, there are 12 unoccupied sites in the cell and the atoms surrounding these are displaced towards the vacancy, causing further displacements of atoms that are not adjacent to a vacancy. The structure obeys the quasi-linear dependence of occupancy on valence electron concentration first found by Bradley in NiAl. This phenomenon may be interpreted by the two-correlations model which also gives arguments for the different deformation homeotypes and the extra vacancy formation at high valence electron concentrations." @default.
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- W2014286522 title "The crystal structure of nizn3.r" @default.
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