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- W2014304929 abstract "1,1,1,2,3,3-Hexafluoropropane was dehydrofluorinated to yield a 1:1 mixture of (Z)- and (E)-1H-pentafluoropropene. This mixture was found to react with butyl-lithium to give pentafluoropropenyl-lithium, which reacted with a series of carbonyl compounds to give exclusively (Z)- pentafluoropropenyl carbinols. The yields were greater than 50%, indicating that the lithium reagent does not retain its stereochemical identity at low temperature, contrary to the hydrocarbon analog. Hydrolysis of the CF3CFCFLi also gives exclusively the (Z)-F-olefin. Treating (Z)-CF3CFCFC(CF3)2OH with SF4 gave the (E) isomer. Some chemical properties of the carbinols are described." @default.
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- W2014304929 date "1971-07-01" @default.
- W2014304929 modified "2023-09-27" @default.
- W2014304929 title "The preparation and reactions of some carbinols containing the pentafluoropropenyl group" @default.
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- W2014304929 doi "https://doi.org/10.1016/s0022-1139(00)82531-2" @default.
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