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- W2014316874 abstract "We report on studies of the photodissociation spectroscopy of Zn+−methanol complexes in the near-UV region. We observe two absorption bands assigned to Zn+-based 4p ← 4s transitions in a Cs Zn+−OHCH3 association complex. The 22A‘(4pπ) ← 12A‘(4sσ) band shows a significant vibronic resonance structure that can be assigned to a combination of both inter- and intramolecular vibrational modes of the complex. The experimental vibrational frequencies are in excellent agreement with the theoretical model predictions. The higher-energy 22A‘ ‘(4pπ) ← 12A‘(4sσ) band is strongly coupled to a lower lying charge-transfer state and appears as a structureless continuum. We observe very little reactive branching; rather, charge transfer to CH3OH+ + Zn products dominates the dissociation. These results are compared with previous studies of other main-group- and transition-metal-ion−methanol complexes." @default.
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- W2014316874 date "2003-01-23" @default.
- W2014316874 modified "2023-10-11" @default.
- W2014316874 title "Photodissociation Spectroscopy of Zn<sup>+</sup>−Methanol" @default.
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- W2014316874 doi "https://doi.org/10.1021/jp022028y" @default.
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