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- W2014324169 abstract "Abstract The irreversible mechanisms of lithium insertion in amorphous tin composite oxides SnB 0.6 P 0.4 O 2.9 have been studied by X-ray diffraction (XRD) and 119 Sn Mossbauer spectroscopy. The determination of the Lamb–Mossbauer factor has allowed us to evaluate the relative numbers of different tin atoms (Sn II , Sn 0 ). We show that insertion of lithium reduces the Sn II into Sn 0 atoms, which form nanoparticles of active species. The lithium ions act as glass modifiers, breaking the bonds within MOM′ (M, M′=B, P, Sn) bridges and forming non-bridging MO δ − bonds." @default.
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- W2014324169 date "2003-06-01" @default.
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- W2014324169 title "Structural and electronic modifications induced by lithium insertion in Sn-based oxide glasses" @default.
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- W2014324169 doi "https://doi.org/10.1016/s0378-7753(03)00294-5" @default.
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