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- W2014345501 abstract "Acyclic α,α-disubstituted β-phosphonyl esters containing chiral alcoholic auxiliaries were efficiently prepared and evaluated for the lithium naphthalenide-mediated asymmetric reductive alkylation. Among which, the best diastereoselectivity was received from the substrates bearing a (−)-phenylmenthyl group in leading to alkylated esters with up to 83:17 dr. The diastereoselectivity is proven to be controlled by the π-facial differentiation created by the chiral ester as well as the geometry of tetrasubstituted enolates generated by the reductive cleavage of C-P bond." @default.
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- W2014345501 date "2013-01-20" @default.
- W2014345501 modified "2023-10-18" @default.
- W2014345501 title "Chiral Auxiliary Based Reductive Alkylation of α,α-Diallkyl β-Phosphonyl Esters" @default.
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- W2014345501 doi "https://doi.org/10.1002/jccs.201200508" @default.
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