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- W2014346145 abstract "It is shown that, under what may be called an “intermediate” decoupling condition, off-resonance heteronuclear spin decoupling of an abundant spin causes not only a line broadening, but also a line splitting, and a frequency shift of the NMR spectra of the dilute spin in solids. Typical examples of the fineshape behavior as a function of off-resonance decoupling frequency are presented and analyzed for the CH, CH2, and CH3 carbon nuclei in a single crystal of dimedone. The quadratic dependence of the linewidth on the off-resonance decoupling frequency, under the “strong near resonance” decoupling condition, is examined for both the single-crystal case, and for the CP-MAS spectrum of dimedone." @default.
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- W2014346145 date "1986-01-01" @default.
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- W2014346145 title "Off resonance heteronuclear spin-decoupling in solids" @default.
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- W2014346145 doi "https://doi.org/10.1016/0022-2364(86)90100-9" @default.
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