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- W2014351185 abstract "Optical absorption, power rotary and circular dichroism of crystals of the sillenite family Bi12MxI20(M- elements I-VIII of groups or their combination) were measured. The t1-2e charge transfer transition of the [VO4]3- tetrahedral complexes is found to make a negative contribution to the optical rotation of the vanadium sillenite. We present a model, which takes into account a negative contribution from the charge-transfer transitions of [MO4]n- complexes to the optical rotation in Bi12MxO20 crystals. It was found that M vacancies and crystal field transitions of 3d- elements contribute significantly to the circular dichroism of sillenite crystals.© (2001) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only." @default.
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- W2014351185 date "2001-03-15" @default.
- W2014351185 modified "2023-09-23" @default.
- W2014351185 title "<title>Optical activity and circular dichroism in the sillenite crystals</title>" @default.
- W2014351185 doi "https://doi.org/10.1117/12.418837" @default.
- W2014351185 hasPublicationYear "2001" @default.
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