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• W2014367828 abstract "Silsesquioxane microgel nanoparticles characterized by low diameters (below 30 nm) and reduced polydispersity can be produced in an acid-catalyzed sol–gel process in an aqueous microemulsion. Suitable surface modification of such structures leads to macroinitiators for atom-transfer radical polymerization (ATRP). This polymerization method was applied in order to graft polystyrene chains onto the surface of the microgels. Well-defined structures exhibiting a core-shell architecture were produced with the Mw of grafted polymers ranging from 8.5 to about 30 kg/mol. The products were extensively characterized with light scattering, X-ray scattering, thermal analysis (TGA/DSC) and microscopy (TEM/SEM) to obtain information on parameters characterizing polystyrene brush. Polymer-grafted nanoparticles will be used for the modification of homopolymer and block copolymer matrices." @default.
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• W2014367828 date "2008-02-01" @default.
• W2014367828 modified "2023-10-01" @default.
• W2014367828 title "Well-defined core-shell structures based on silsesquioxane microgels: Grafting of polystyrene via ATRP and product characterization" @default.
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• W2014367828 doi "https://doi.org/10.1016/j.polymer.2007.12.030" @default.
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