Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014368659> ?p ?o ?g. }
- W2014368659 endingPage "4722" @default.
- W2014368659 startingPage "4722" @default.
- W2014368659 abstract "The reaction of Group 12 metal dihalides MX2 with the P,N-ligands [Fe(C5H4-PPh2)(C5H4-2-py)] (1) (2-py = pyrid-2-yl), [Fe(C5H4-PPh2)(C5H4-CH2-2-py)] (2) and [Fe(C5H4-PPh2)(C5H4-3-py)] (3) (3-py = pyrid-3-yl) was investigated. For a 1 : 1 molar ratio of MX2 and the respective ligand, three structure types were found in the solid state, viz. chelate, cyclic dimer and chain-like coordination polymer. The MII coordination environment is distorted pseudo-tetrahedral in each case. The P–M–N angle is much larger in the chelates (≥119°) than in the ligand-bridged structures (≤109°). 1 prefers the formation of chelates [MX2(1-κ2N,P)]. 3 forms coordination polymers [MX2(μ-3)]n. With the more flexible 2 all three structure types can occur. Dynamic coordination equilibria were observed in solution for the molecular complexes obtained with 1 and 2. NMR data indicate that the N- and P-donor sites interact most strongly with ZnII and HgII, respectively. While the formation of bis(phosphine)mercury complexes (soft–soft) was easily achieved, no bis(pyridine)zinc complex (borderline–borderline) could be obtained, which is surprising in view of the HSAB principle." @default.
- W2014368659 created "2016-06-24" @default.
- W2014368659 creator A5006835259 @default.
- W2014368659 creator A5009121433 @default.
- W2014368659 creator A5060305268 @default.
- W2014368659 creator A5079812965 @default.
- W2014368659 creator A5082191490 @default.
- W2014368659 date "2011-01-01" @default.
- W2014368659 modified "2023-10-11" @default.
- W2014368659 title "The coordination behaviour of ferrocene-based pyridylphosphine ligands towards ZnII, CdII and HgII" @default.
- W2014368659 cites W1965272987 @default.
- W2014368659 cites W1967019492 @default.
- W2014368659 cites W1967908946 @default.
- W2014368659 cites W1970688390 @default.
- W2014368659 cites W1974383634 @default.
- W2014368659 cites W1976075691 @default.
- W2014368659 cites W1976622176 @default.
- W2014368659 cites W1985975608 @default.
- W2014368659 cites W1986549550 @default.
- W2014368659 cites W1990721410 @default.
- W2014368659 cites W1993839976 @default.
- W2014368659 cites W1994777748 @default.
- W2014368659 cites W1995676881 @default.
- W2014368659 cites W1996273492 @default.
- W2014368659 cites W1998683053 @default.
- W2014368659 cites W1999526688 @default.
- W2014368659 cites W1999605153 @default.
- W2014368659 cites W1999892764 @default.
- W2014368659 cites W2004246465 @default.
- W2014368659 cites W2005308865 @default.
- W2014368659 cites W2005805840 @default.
- W2014368659 cites W2005877813 @default.
- W2014368659 cites W2008568336 @default.
- W2014368659 cites W2010837956 @default.
- W2014368659 cites W2014338534 @default.
- W2014368659 cites W2015732414 @default.
- W2014368659 cites W2016082316 @default.
- W2014368659 cites W2019657972 @default.
- W2014368659 cites W2020042245 @default.
- W2014368659 cites W2024554949 @default.
- W2014368659 cites W2030434568 @default.
- W2014368659 cites W2030627145 @default.
- W2014368659 cites W2042851487 @default.
- W2014368659 cites W2046947612 @default.
- W2014368659 cites W2047755968 @default.
- W2014368659 cites W2048046732 @default.
- W2014368659 cites W2051864945 @default.
- W2014368659 cites W2053823238 @default.
- W2014368659 cites W2055789018 @default.
- W2014368659 cites W2059209248 @default.
- W2014368659 cites W2060955206 @default.
- W2014368659 cites W2063334178 @default.
- W2014368659 cites W2064217658 @default.
- W2014368659 cites W2064783855 @default.
- W2014368659 cites W2069266641 @default.
- W2014368659 cites W2069311299 @default.
- W2014368659 cites W2070734212 @default.
- W2014368659 cites W2074664906 @default.
- W2014368659 cites W2075670099 @default.
- W2014368659 cites W2077985631 @default.
- W2014368659 cites W2080564944 @default.
- W2014368659 cites W2083228395 @default.
- W2014368659 cites W2084517808 @default.
- W2014368659 cites W2086922462 @default.
- W2014368659 cites W2087425194 @default.
- W2014368659 cites W2090739083 @default.
- W2014368659 cites W2091748268 @default.
- W2014368659 cites W2092315973 @default.
- W2014368659 cites W2093219653 @default.
- W2014368659 cites W2096374070 @default.
- W2014368659 cites W2098209567 @default.
- W2014368659 cites W2103420011 @default.
- W2014368659 cites W2109372033 @default.
- W2014368659 cites W2110268970 @default.
- W2014368659 cites W2116776591 @default.
- W2014368659 cites W2118431584 @default.
- W2014368659 cites W2121237359 @default.
- W2014368659 cites W2129193545 @default.
- W2014368659 cites W2131350133 @default.
- W2014368659 cites W2135261637 @default.
- W2014368659 cites W2144486442 @default.
- W2014368659 cites W2145538332 @default.
- W2014368659 cites W2148894751 @default.
- W2014368659 cites W2152529276 @default.
- W2014368659 cites W2160923526 @default.
- W2014368659 cites W2167590372 @default.
- W2014368659 cites W2168625548 @default.
- W2014368659 cites W2321983227 @default.
- W2014368659 cites W2331215636 @default.
- W2014368659 cites W2950074726 @default.
- W2014368659 cites W2950393955 @default.
- W2014368659 cites W2950780956 @default.
- W2014368659 cites W2953335984 @default.
- W2014368659 cites W3138792293 @default.
- W2014368659 cites W4244877269 @default.
- W2014368659 cites W4256234511 @default.
- W2014368659 cites W1973946090 @default.
- W2014368659 doi "https://doi.org/10.1039/c0dt01810d" @default.