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- W2014373694 abstract "Abstract Measurements are described of the paramagnetic susceptibilities of Co 3 O 4 , ZnCo 2 O 4 , and mixed crystals of ZnAl 2 O 4 ‐ZnCo 2 O 4 and the results are given in a table of X ‐values and two plots of 1/ X against absolute temperature. To explain the very low value of the mean Bohr magneton number, found for these compounds, the assumption is made that Co 3+ in these spinel structures is situated at octahedral interstices and covalently bonded as in the other complex compounds of Co III , thus not contributing to the paramagnetism. This assumption gives the reasonable, although somewhat high value of 4.7 μ B for the Co 2+ ion in Co 3 O 4 . This high value of μ for Co 2+ and the weak paramagnetism of ZnCo 2 O 4 may be caused by a slight oxygen deficiency of the compounds or a small energy difference between the diamagnetic and paramagnetic states of Co 3+ in octahedra." @default.
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- W2014373694 date "1956-01-01" @default.
- W2014373694 modified "2023-10-17" @default.
- W2014373694 title "Structure and magnetic properties of Co3O4 and ZnCo2O4" @default.
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- W2014373694 doi "https://doi.org/10.1002/recl.19560750913" @default.
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