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- W2014374437 abstract "The π hydrogen bonding between phenol and monoolefins has been studied by examining the OH stretching vibration spectra of phenol in the presence of monoolefins. From comparison of the hydrogen bond shifts, it has been shown that the basicity of the aliphatic olefins toward phenol increases with the increasing alkylsubstitution on the double bond carbon. The endo-cyclic olefins are more basic than RCH=CH2 and RCH=CHR′ where R and R′ represent alkyl groups. The equilibrium constants for complex formation with olefins were smaller than those with aromatic hydrocarbons. The steric effects on the hydrogen bond complex with aliphatic and endocyclic olefins have been discussed." @default.
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- W2014374437 modified "2023-10-18" @default.
- W2014374437 title "Intermolecular Hydrogen Bond Involving a π Base as the Proton Acceptor. IX. Hydrogen Bonding of Phenol to Monoolefins" @default.
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- W2014374437 doi "https://doi.org/10.1246/bcsj.42.3263" @default.
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