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- W201437450 startingPage "2023" @default.
- W201437450 abstract "Dibenzyl sulfide was oxidized at the a-carbon to yield benzaldehyde in the presence of <TEX>$Pd(NO_3)_2$</TEX>. Oxygen itself could not oxidize the sulfide directly, instead the nitrato ligand of the palladium complex transferred oxygen to dibenzyl sulfide to form benzaldehyde. The X-ray crystal structure of the intermediate complex, cis-[<TEX>$Pd(NO_3)_2$</TEX>{<TEX>$S(CH_2C_6H_5)_2$</TEX>}<TEX>$_2$</TEX>], revealed that the nitrato ligand was unidentate. Para-substituted dibenzyl sulfides I, <TEX>$(YC_6H_4CH_2)_2S $</TEX>wherein Y = <TEX>$OCH_3$</TEX>, <TEX>$CH_3$</TEX>, Cl, CN, or <TEX>$NO_2$</TEX>, were synthesized and reacted with palladium nitrate, and those with electron-donating substituents (Y = <TEX>$OCH_3$</TEX> and <TEX>$CH_3$</TEX>) were good substrates for the oxidation reaction with palladium nitrate. Thus, the reaction mechanism of the oxygen transfer was proposed to include nucleophilic benzylic carbon." @default.
- W201437450 created "2016-06-24" @default.
- W201437450 date "2006-12-20" @default.
- W201437450 modified "2023-10-17" @default.
- W201437450 title "Oxidation of Dibenzyl Sulfide via an Oxygen Transfer from Palladium Nitrate" @default.
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- W201437450 doi "https://doi.org/10.5012/bkcs.2006.27.12.2023" @default.
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