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- W2014376946 abstract "The absorption and fluorescence spectra of syringaldazine (SYAZ) has been recorded in solvents of different polarity, pH and β-cyclodextrin (β-CD) and compared with syringaldehyde (SYAL). The inclusion complex of SYAZ with β-CD is investigated by UV–vis, fluorimetry, AM 1, FT-IR, 1H NMR and scanning electron microscope (SEM). ΔG value suggests the inclusion process is an exothermic and spontaneous. In all solvents a dual fluorescence is observed for SYAZ, whereas, SYAL shows a dual luminescence only in polar solvents. The excitation spectra for the 410 nm is different from 340 nm indicate two different species present in this molecule. In pH solutions: (i) a large red shifted maxima is observed in the dianion and is due to large interactions between the aromatic ring and (ii) the large blue shift at pH ∼4.5, is due to dissociation of azine group and formation of aldehyde. β-CD studies reveal that, SYAZ forms a 1:2 complex from 1:1 complex with β-CD." @default.
- W2014376946 created "2016-06-24" @default.
- W2014376946 creator A5002176605 @default.
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- W2014376946 date "2007-11-01" @default.
- W2014376946 modified "2023-09-27" @default.
- W2014376946 title "Dual fluorescence of syringaldazine" @default.
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- W2014376946 doi "https://doi.org/10.1016/j.saa.2007.01.004" @default.
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