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- W2014378876 abstract "The effect of cobalt on the structure and reducibility of a series of cobalt-promoted, molybdena-alumina catalysts was studied. Preparational variables were: Co and Mo levels, order of addition, and calcination temperature and environment. Catalysts were characterized by various instrumental techniques and reduction in H2 at 500 °C. Mo/Al2O3 catalysts exhibited a variable strength of interaction of Mo with the Al2O3. For Co/Al2O3 catalysts, two separate phases were found, a Co-Al2O3 interaction phase, which was nonreducible, and a well-defined Co3O4 phase, which reduced to Co metal. When Mo was added to Co/Al2O3 catalysts, the Co and Mo phases were essentially the same as for the individual catalysts. Addition of Co to Mo/Al2O3 catalysts, however, resulted in an interaction between Co and Mo. In coimpregnated catalysts, bulk CoMoO4 was observed when Co ≥ 2%. Relative amounts of the various phases were greatly dependent upon preparation and calcination conditions." @default.
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- W2014378876 date "1980-08-01" @default.
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- W2014378876 title "Studies on molybdena-alumina catalysts *1VII. Effect of cobalt on catalyst states and reducibility" @default.
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- W2014378876 doi "https://doi.org/10.1016/0021-9517(80)90506-0" @default.
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