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- W2014384154 abstract "The infrared and Raman band profile and band-width of the crystalline halides (CH 3 ) 3 NH + X − in the v (NH) stretching vibration region are analyzed with the help of the temperature dependence and of the isotopic substitution effect. While the infrared v (NH) band-width is several times larger than the Raman linewidth in the pure substance, the widths are about the same in the isotopic diluted system (CH 3 ) 3 NH + Cl − /(CH 3 ) 3 ND + Cl − . This result is explained by induced cooperative effects increasing strongly the anharmonicity of the electrical moment and not that of the polarizability of the NH oscillators." @default.
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- W2014384154 date "1974-07-01" @default.
- W2014384154 modified "2023-09-23" @default.
- W2014384154 title "Raman and infrared band shapes of the NH+...X-hydrogen bond in trimethylaminium halide crystals" @default.
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- W2014384154 doi "https://doi.org/10.1016/0009-2614(74)80456-2" @default.
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