Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014386460> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2014386460 endingPage "668" @default.
- W2014386460 startingPage "661" @default.
- W2014386460 abstract "The standard molar enthalpies of formation of crystalline chelates M(thd)3, (M=Sc, Y, La; and thd=2,2,6,6-tetramethyl-3,5-heptanedionate), determined by reaction-solution calorimetry atT=(298.15±0.02) K, were found to be −(2317.83±11.7) kJ · mol−1, −(2386.1±11.4) kJ · mol−1, and −(2442.2±11.8) kJ · mol−1, respectively. The corresponding molar enthalpies of sublimation, (79.6±2.4) kJ · mol−1, 117 kJ · mol−1, and (156.0±4.6) kJ · mol−1, were obtained by differential scanning calorimetry or vapour pressure measurements, and enabled the calculation of the standard molar enthalpies of formation of the gaseous chelates. From the standard molar enthalpies of dissociation of the chelates (1575±62) kJ · mol−1, (1652±62) kJ · mol−1, and (1679±62) kJ · mol−1, respectively, the mean metal-to-oxygen bond enthalpies were also calculated to be (263±10) kJ · mol−1, (275±10) kJ · mol−1, and (280±10) kJ · mol−1, by assuming the equivalence of all bonds in the chelates. This first sequence of values obtained for the scandium group elements showed a tendency towards an increase of values with the increase of the metal's atomic number in this series." @default.
- W2014386460 created "2016-06-24" @default.
- W2014386460 creator A5046261053 @default.
- W2014386460 creator A5068656306 @default.
- W2014386460 creator A5081019817 @default.
- W2014386460 date "1997-06-01" @default.
- W2014386460 modified "2023-10-14" @default.
- W2014386460 title "Thermochemical studies of 2,2,6,6-tetramethyl-3,5-heptanedione chelates of scandium group elements" @default.
- W2014386460 doi "https://doi.org/10.1006/jcht.1996.0187" @default.
- W2014386460 hasPublicationYear "1997" @default.
- W2014386460 type Work @default.
- W2014386460 sameAs 2014386460 @default.
- W2014386460 citedByCount "13" @default.
- W2014386460 countsByYear W20143864602013 @default.
- W2014386460 countsByYear W20143864602014 @default.
- W2014386460 countsByYear W20143864602016 @default.
- W2014386460 countsByYear W20143864602017 @default.
- W2014386460 countsByYear W20143864602023 @default.
- W2014386460 crossrefType "journal-article" @default.
- W2014386460 hasAuthorship W2014386460A5046261053 @default.
- W2014386460 hasAuthorship W2014386460A5068656306 @default.
- W2014386460 hasAuthorship W2014386460A5081019817 @default.
- W2014386460 hasConcept C113196181 @default.
- W2014386460 hasConcept C121332964 @default.
- W2014386460 hasConcept C147368240 @default.
- W2014386460 hasConcept C147789679 @default.
- W2014386460 hasConcept C15744967 @default.
- W2014386460 hasConcept C178790620 @default.
- W2014386460 hasConcept C179104552 @default.
- W2014386460 hasConcept C185592680 @default.
- W2014386460 hasConcept C19184958 @default.
- W2014386460 hasConcept C202270520 @default.
- W2014386460 hasConcept C29563950 @default.
- W2014386460 hasConcept C542102704 @default.
- W2014386460 hasConcept C544153396 @default.
- W2014386460 hasConcept C551831248 @default.
- W2014386460 hasConcept C58437636 @default.
- W2014386460 hasConcept C97355855 @default.
- W2014386460 hasConceptScore W2014386460C113196181 @default.
- W2014386460 hasConceptScore W2014386460C121332964 @default.
- W2014386460 hasConceptScore W2014386460C147368240 @default.
- W2014386460 hasConceptScore W2014386460C147789679 @default.
- W2014386460 hasConceptScore W2014386460C15744967 @default.
- W2014386460 hasConceptScore W2014386460C178790620 @default.
- W2014386460 hasConceptScore W2014386460C179104552 @default.
- W2014386460 hasConceptScore W2014386460C185592680 @default.
- W2014386460 hasConceptScore W2014386460C19184958 @default.
- W2014386460 hasConceptScore W2014386460C202270520 @default.
- W2014386460 hasConceptScore W2014386460C29563950 @default.
- W2014386460 hasConceptScore W2014386460C542102704 @default.
- W2014386460 hasConceptScore W2014386460C544153396 @default.
- W2014386460 hasConceptScore W2014386460C551831248 @default.
- W2014386460 hasConceptScore W2014386460C58437636 @default.
- W2014386460 hasConceptScore W2014386460C97355855 @default.
- W2014386460 hasIssue "6" @default.
- W2014386460 hasLocation W20143864601 @default.
- W2014386460 hasOpenAccess W2014386460 @default.
- W2014386460 hasPrimaryLocation W20143864601 @default.
- W2014386460 hasRelatedWork W1974599467 @default.
- W2014386460 hasRelatedWork W1980208500 @default.
- W2014386460 hasRelatedWork W1984401565 @default.
- W2014386460 hasRelatedWork W1985657952 @default.
- W2014386460 hasRelatedWork W2014386460 @default.
- W2014386460 hasRelatedWork W2017508049 @default.
- W2014386460 hasRelatedWork W2034490172 @default.
- W2014386460 hasRelatedWork W2094599096 @default.
- W2014386460 hasRelatedWork W2131975752 @default.
- W2014386460 hasRelatedWork W2208885888 @default.
- W2014386460 hasVolume "29" @default.
- W2014386460 isParatext "false" @default.
- W2014386460 isRetracted "false" @default.
- W2014386460 magId "2014386460" @default.
- W2014386460 workType "article" @default.