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- W2014387966 abstract "The products of the decomposition of allyl peroxides 1–5, initiated by tert-butyl peracetate, in three solvents—cyclohexane, dimethyl malonate and benzene—were analysed. The formation of epoxides proved the existence of an homolytic induced decomposition of the unsaturated peroxides by a chain process involving a free radical addition to the double bond and an intramolecular homolytic substitution on the peroxide linkage. The balance of the reaction's products indicated a second way of degradation of the peroxides: allylic hydrogen abstraction followed by the breaking of the peroxide bond by β-elimination. The relative ratios of the products generated by the eliminated alkoxy radicals YO˙ and of the different epoxides produced in these reactions showed the influence of the polar factors in the various steps of the homolytic induced decomposition: i.e. hydrogen abstraction to the solvent or to the peroxide and addition to the double bond." @default.
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- W2014387966 date "1994-01-01" @default.
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- W2014387966 title "Intramolecular homolytic displacements. Part 22. Polar effects in the homolytic induced decompositions of allyl peroxides" @default.
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- W2014387966 doi "https://doi.org/10.1039/p29940000745" @default.
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