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- W2014397304 abstract "The effect of added electrolyte on micelle-catalyzed reaction was analyzed. The log [L.S] vs. log (total counter ion concentration) plot gives a straight line, where [L.S] is a limiting slope on a rate-surfactant concentration plot at an infinitely dilute micellar concentration. The slope is related to the number and the magnitude of the Coulombic term that may be included in the concentration effect of reactants, and in the intrinsic micellar effect, or the relative stabilization of a transition state in the presence of micelles. The above treatment was applied to (1) the hydrolysis of trimethyl orthobenzoate in sodium dodecyl sulfate solution, (2) the fading reaction of Crystal Violet in hexadecyltrimethylammonium bromide (CTABr) solution, and (3) the nucleophilic substitution reaction of 2,4-dinitrofluorobenzene in CTABr solution. It was found that the concentration effect is predominant in (1), while the relative stabilization of the transition state occurs in (2) and (3) in addition to the concentration effect." @default.
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- W2014397304 date "1976-10-01" @default.
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- W2014397304 title "Analysis of the Effect of Added Electrolyte on the Micellar Catalysis" @default.
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- W2014397304 doi "https://doi.org/10.1246/bcsj.49.2731" @default.
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