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- W2014403897 abstract "The coordination of nitric oxide (NO) to cobalt(II) phthalocyanine (CoPc) in dimethyl sulphoxide (DMSO) has been studied. CoPc coordinates with NO in a 1:1 ratio, forming a CoPc(NO) species. The IR band observed at 1680 cm−1 is assigned to the coordinated NO. In the presence of excess NO, pseudo first order kinetics were followed. The observed rate constant, kf, was determined to be 15.0±0.3 dm−3 mol−1 s−1 and the equilibrium constant was K=5.4±0.4×104dm3 mol−1. Solution or adsorbed CoPc catalyses the reduction of NO. The products of reduction include NH3 and NH2OH." @default.
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- W2014403897 title "Interaction of nitric oxide with cobalt(II) phthalocyanine: kinetics, equilibria and electrocatalytic studies" @default.
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- W2014403897 doi "https://doi.org/10.1016/s0277-5387(98)00244-7" @default.
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