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- W2014405144 abstract "The hydrophobic indigo derivative N,N′-dimyristoylindigo (DMI) is tested as a probe for photochemistry in hydrocarbons and other non-aqueous media. Quantum yields of trans → cis and cis → trans photoisomerization and dark cis → trans reversion rates were determined when possible in 26 organic solvents of various types. The trans → cis isomerization quantum yield is highest in hydrocarbons and low in strongly polar solvents; the cis → trans quantum yield varies less with solvent type. There are significant differences among trans → cis quantum yields at different wavelengths in benzene and acetonitrile. The trans-DMI visible band position and intensity show some dependence on solvent type but little on refractive index or dielectric constant per se. The dark reversion rate is highest in alcohols but variable in all solvents, suggesting that cis conformers of varying degrees of stability are formed." @default.
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- W2014405144 modified "2023-09-27" @default.
- W2014405144 title "Photoisomerization of dimyristoylindigo: rates in various solvents" @default.
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- W2014405144 doi "https://doi.org/10.1016/0047-2670(84)80019-2" @default.
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