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- W2014405819 abstract "ansa-Tetramethyldisiloxane-bridged indenyl, tetrahydroindenyl and cyclopentadienyl zirconium complexes 1–4 were prepared. The pure rac-1–3 and meso-1–2 complexes were separated by fractional crystallization. Indenyl complexes, both rac-1 and meso-1, in the presence of methylaluminoxane (MAO), have very high activities for ethylene polymerization. The molecular weight of polyethylene produced with rac-1 is extremely high and significantly dependent on polymerization temperature. The tert-butyl-substituted cyclopentadienyl complex exhibits low activity and produces polyethylene of low molecular weight." @default.
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- W2014405819 date "1997-10-01" @default.
- W2014405819 modified "2023-10-11" @default.
- W2014405819 title "Ethylene polymerizations with disiloxane-bridged indenyl and cyclopentadienyl metallocene catalysts" @default.
- W2014405819 doi "https://doi.org/10.1002/macp.1997.021981017" @default.
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