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- W2014406579 abstract "The Keggin-type di-iron-substituted silicotungstate, γ-SiW10{Fe(OH2)}2O386−, can catalyze the selective oxidation of various alkanes including methane with hydrogen peroxide. The tetrabutylammonium salt catalytically oxidized cyclohexane, n-hexane, n-pentane, and adamantane in acetonitrile. Even lower alkanes such as methane, ethane, propane, and n-butane were catalytically oxidized. It is remarkable that the efficiency of hydrogen peroxide utilization to oxygenated products reached up to ca. 100% for the oxidation of cyclohexane and adamantane. The efficiency and activity for the utilization of hydrogen peroxide greatly depended on the iron centers and di-iron-substituted γ-SiW10{Fe(OH2)}2O386− showed the highest efficiency of hydrogen peroxide utilization and conversion. Such a structure dependency of the catalysis is significant and the remarkable catalytic performance of di-iron-substituted polyoxometalate may be related to the catalysis by methane monooxygenase. It was also demonstrated that the water-soluble potassium salt catalytically oxidized the lower alkanes with hydrogen peroxide in water." @default.
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- W2014406579 date "2006-01-02" @default.
- W2014406579 modified "2023-09-30" @default.
- W2014406579 title "Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates" @default.
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- W2014406579 doi "https://doi.org/10.1007/0-306-47625-8_22" @default.
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