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- W2014408053 abstract "A Mannich base derivative of 5,11,17,23-tetrakis-[(1,4-dioxa-8-azaspiro-[4.5]decanyl)methyl]-25,26,27,28-tetrahydroxy calix[4]arene 3 was synthesized by the treatment of calix[4]arene with a cyclic secondary amine (1,4-dioxa-8-azaspiro-[4.5]decane) and formaldehyde. The compound 3 was treated with dibromoxylene to obtain a calix[4]arene-based copolymer 4. In batch sorption experiments of selected carcinogenic azo dyes and aromatic amines, the compounds 3 and 4 were found to be a better sorbent for azo dyes than for the aromatic amines. It was observed that the percentage of azo dye removal was 95-99% for compound 3 and 83-97% for 4 when the pH of the dye solution was in the range of 2.0-8.0. The sorption of azo dyes and aromatic amines by calix[4]arenes-based compounds indicates that amino groups play the major role for the formation of hydrogen bonds and electrostatic interactions." @default.
- W2014408053 created "2016-06-24" @default.
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- W2014408053 date "2009-03-01" @default.
- W2014408053 modified "2023-09-29" @default.
- W2014408053 title "Removal efficiency of a calix[4]arene-based polymer for water-soluble carcinogenic direct azo dyes and aromatic amines" @default.
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- W2014408053 doi "https://doi.org/10.1016/j.jhazmat.2008.05.127" @default.
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