Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014429209> ?p ?o ?g. }
- W2014429209 endingPage "590" @default.
- W2014429209 startingPage "580" @default.
- W2014429209 abstract "Abstract The kinetics and mechanism for the thermal decomposition of diketene have been studied in the temperature range 510–603 K using highly diluted mixtures with Ar as a diluent. The concentrations of diketene, ketene, and CO 2 were measured by FTIR spectrometry using calibrated standard mixtures. Two reaction channels were identified. The rate constants for the formation of ketene ( k 1 ) and CO 2 ( k 2 ) have been determined and compared with the values predicted by the Rice–Ramsperger–Kassel–Marcus (RRKM) theory for the branching reaction. The first‐order rate constants, k 1 (s −1 ) = 10 15.74 ± 0.72 exp(−49.29 (kcal mol −1 ) (±1.84)/RT) and k 2 (s −1 ) = 10 14.65 ± 0.87 exp(−49.01 (kcal mol −1 ) (±2.22)/RT); the bulk of experimental data agree well with predicted results. The heats of formation of ketene, diketene, cyclobuta‐1,3‐dione, and cyclobuta‐1,2‐dione at 298 K computed from the G2M scheme are −11.1, −45.3, −43.6, and −40.3 kcal mol −1 , respectively. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 580–590, 2007" @default.
- W2014429209 created "2016-06-24" @default.
- W2014429209 creator A5011722221 @default.
- W2014429209 creator A5079499795 @default.
- W2014429209 creator A5081159136 @default.
- W2014429209 creator A5085445579 @default.
- W2014429209 date "2007-07-23" @default.
- W2014429209 modified "2023-10-10" @default.
- W2014429209 title "Theoretical and experimental studies of the diketene system: Product branching decomposition rate constants and energetics of isomers" @default.
- W2014429209 cites W1579327726 @default.
- W2014429209 cites W1966874967 @default.
- W2014429209 cites W1969209996 @default.
- W2014429209 cites W1973367099 @default.
- W2014429209 cites W1981583927 @default.
- W2014429209 cites W1984410901 @default.
- W2014429209 cites W1985847796 @default.
- W2014429209 cites W1986922432 @default.
- W2014429209 cites W1989162753 @default.
- W2014429209 cites W1995626848 @default.
- W2014429209 cites W2006947086 @default.
- W2014429209 cites W2014767176 @default.
- W2014429209 cites W2020140400 @default.
- W2014429209 cites W2022561314 @default.
- W2014429209 cites W2030822544 @default.
- W2014429209 cites W2032960017 @default.
- W2014429209 cites W2035376963 @default.
- W2014429209 cites W2040195084 @default.
- W2014429209 cites W2044548753 @default.
- W2014429209 cites W2048559292 @default.
- W2014429209 cites W2054063376 @default.
- W2014429209 cites W2077528747 @default.
- W2014429209 cites W2078086290 @default.
- W2014429209 cites W2079458939 @default.
- W2014429209 cites W2081004295 @default.
- W2014429209 cites W2095175581 @default.
- W2014429209 cites W2095467541 @default.
- W2014429209 cites W2108038777 @default.
- W2014429209 cites W2143981217 @default.
- W2014429209 cites W2165996419 @default.
- W2014429209 cites W2318612674 @default.
- W2014429209 cites W2324775913 @default.
- W2014429209 cites W2327545613 @default.
- W2014429209 cites W277706964 @default.
- W2014429209 cites W2949625916 @default.
- W2014429209 cites W2950867589 @default.
- W2014429209 cites W4232603018 @default.
- W2014429209 doi "https://doi.org/10.1002/kin.20263" @default.
- W2014429209 hasPublicationYear "2007" @default.
- W2014429209 type Work @default.
- W2014429209 sameAs 2014429209 @default.
- W2014429209 citedByCount "5" @default.
- W2014429209 countsByYear W20144292092012 @default.
- W2014429209 countsByYear W20144292092023 @default.
- W2014429209 crossrefType "journal-article" @default.
- W2014429209 hasAuthorship W2014429209A5011722221 @default.
- W2014429209 hasAuthorship W2014429209A5079499795 @default.
- W2014429209 hasAuthorship W2014429209A5081159136 @default.
- W2014429209 hasAuthorship W2014429209A5085445579 @default.
- W2014429209 hasConcept C121332964 @default.
- W2014429209 hasConcept C124681953 @default.
- W2014429209 hasConcept C147368240 @default.
- W2014429209 hasConcept C147597530 @default.
- W2014429209 hasConcept C147789679 @default.
- W2014429209 hasConcept C148898269 @default.
- W2014429209 hasConcept C155647269 @default.
- W2014429209 hasConcept C160434732 @default.
- W2014429209 hasConcept C178790620 @default.
- W2014429209 hasConcept C184779094 @default.
- W2014429209 hasConcept C185592680 @default.
- W2014429209 hasConcept C18705241 @default.
- W2014429209 hasConcept C206175624 @default.
- W2014429209 hasConcept C2778659974 @default.
- W2014429209 hasConcept C2778874822 @default.
- W2014429209 hasConcept C32909587 @default.
- W2014429209 hasConcept C46460574 @default.
- W2014429209 hasConcept C62520636 @default.
- W2014429209 hasConcept C93391505 @default.
- W2014429209 hasConceptScore W2014429209C121332964 @default.
- W2014429209 hasConceptScore W2014429209C124681953 @default.
- W2014429209 hasConceptScore W2014429209C147368240 @default.
- W2014429209 hasConceptScore W2014429209C147597530 @default.
- W2014429209 hasConceptScore W2014429209C147789679 @default.
- W2014429209 hasConceptScore W2014429209C148898269 @default.
- W2014429209 hasConceptScore W2014429209C155647269 @default.
- W2014429209 hasConceptScore W2014429209C160434732 @default.
- W2014429209 hasConceptScore W2014429209C178790620 @default.
- W2014429209 hasConceptScore W2014429209C184779094 @default.
- W2014429209 hasConceptScore W2014429209C185592680 @default.
- W2014429209 hasConceptScore W2014429209C18705241 @default.
- W2014429209 hasConceptScore W2014429209C206175624 @default.
- W2014429209 hasConceptScore W2014429209C2778659974 @default.
- W2014429209 hasConceptScore W2014429209C2778874822 @default.
- W2014429209 hasConceptScore W2014429209C32909587 @default.
- W2014429209 hasConceptScore W2014429209C46460574 @default.
- W2014429209 hasConceptScore W2014429209C62520636 @default.
- W2014429209 hasConceptScore W2014429209C93391505 @default.
- W2014429209 hasIssue "10" @default.
- W2014429209 hasLocation W20144292091 @default.