Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014450504> ?p ?o ?g. }
- W2014450504 endingPage "549" @default.
- W2014450504 startingPage "549" @default.
- W2014450504 abstract "Dithiobenzoic acid (DTBA) induces controlled polymerization behaviour in methyl methacrylate polymerization at 60°C, accompanied by a pronounced induction period of several hours. DTBA is partially transformed during this induction period into a dithioester with a tertiary ester group moiety, which constitutes an efficient reversible addition–fragmentation chain transfer (RAFT) agent. The transformation reaction is proposed to proceed via a hydrogen abstraction from DTBA by radicals and subsequent termination of the formed phenylcarbonothioylsulfanyl radical with propagating radicals. The proposed reaction scheme was implemented into a computer model, by which the rate coefficient of the hydrogen abstraction from DTBA and of the reinitiation of the intermediate phenylcarbonothioylsulfanyl radical was estimated. The model is in agreement with all of the species observable by electrospray ionization mass spectrometry, with the extent of the experimental induction periods, and with the absolute concentrations of dithioesters that act as efficient RAFT agents during the polymerization. A protocol that uses a cocktail of initiators is introduced, by which the induction period in DTBA-mediated polymerization is effectively eliminated." @default.
- W2014450504 created "2016-06-24" @default.
- W2014450504 creator A5026867291 @default.
- W2014450504 creator A5061936150 @default.
- W2014450504 date "2006-01-01" @default.
- W2014450504 modified "2023-10-12" @default.
- W2014450504 title "On the Mechanism of Radical Polymerization of Methyl Methacrylate with Dithiobenzoic Acid as Mediator" @default.
- W2014450504 cites W1544218798 @default.
- W2014450504 cites W1965541763 @default.
- W2014450504 cites W1970364168 @default.
- W2014450504 cites W1978872559 @default.
- W2014450504 cites W1984682193 @default.
- W2014450504 cites W1987559294 @default.
- W2014450504 cites W1989582314 @default.
- W2014450504 cites W1993885477 @default.
- W2014450504 cites W1997033061 @default.
- W2014450504 cites W1997300826 @default.
- W2014450504 cites W1998811418 @default.
- W2014450504 cites W2005531118 @default.
- W2014450504 cites W2010018976 @default.
- W2014450504 cites W2017928816 @default.
- W2014450504 cites W2018158102 @default.
- W2014450504 cites W2020026722 @default.
- W2014450504 cites W2020671125 @default.
- W2014450504 cites W2026495887 @default.
- W2014450504 cites W2028632396 @default.
- W2014450504 cites W2030363892 @default.
- W2014450504 cites W2030753006 @default.
- W2014450504 cites W2032884764 @default.
- W2014450504 cites W2034664032 @default.
- W2014450504 cites W2035396074 @default.
- W2014450504 cites W2035761220 @default.
- W2014450504 cites W2036529073 @default.
- W2014450504 cites W2041671510 @default.
- W2014450504 cites W2043522763 @default.
- W2014450504 cites W2079088301 @default.
- W2014450504 cites W2079207307 @default.
- W2014450504 cites W2098926445 @default.
- W2014450504 cites W2104018884 @default.
- W2014450504 cites W2120126768 @default.
- W2014450504 cites W2128987968 @default.
- W2014450504 cites W2139414379 @default.
- W2014450504 cites W2140464782 @default.
- W2014450504 cites W2150184000 @default.
- W2014450504 cites W2154912073 @default.
- W2014450504 cites W2156003679 @default.
- W2014450504 cites W2159719930 @default.
- W2014450504 cites W2165824463 @default.
- W2014450504 cites W4210975880 @default.
- W2014450504 cites W4238734590 @default.
- W2014450504 doi "https://doi.org/10.1071/ch06158" @default.
- W2014450504 hasPublicationYear "2006" @default.
- W2014450504 type Work @default.
- W2014450504 sameAs 2014450504 @default.
- W2014450504 citedByCount "18" @default.
- W2014450504 countsByYear W20144505042012 @default.
- W2014450504 countsByYear W20144505042016 @default.
- W2014450504 countsByYear W20144505042017 @default.
- W2014450504 countsByYear W20144505042018 @default.
- W2014450504 countsByYear W20144505042021 @default.
- W2014450504 crossrefType "journal-article" @default.
- W2014450504 hasAuthorship W2014450504A5026867291 @default.
- W2014450504 hasAuthorship W2014450504A5061936150 @default.
- W2014450504 hasConcept C111919701 @default.
- W2014450504 hasConcept C111998727 @default.
- W2014450504 hasConcept C121120078 @default.
- W2014450504 hasConcept C139066938 @default.
- W2014450504 hasConcept C161790260 @default.
- W2014450504 hasConcept C178790620 @default.
- W2014450504 hasConcept C185592680 @default.
- W2014450504 hasConcept C188027245 @default.
- W2014450504 hasConcept C191015642 @default.
- W2014450504 hasConcept C2776568683 @default.
- W2014450504 hasConcept C2777935641 @default.
- W2014450504 hasConcept C34594497 @default.
- W2014450504 hasConcept C41008148 @default.
- W2014450504 hasConcept C44228677 @default.
- W2014450504 hasConcept C521977710 @default.
- W2014450504 hasConcept C54175244 @default.
- W2014450504 hasConcept C75473681 @default.
- W2014450504 hasConcept C81022585 @default.
- W2014450504 hasConcept C9132879 @default.
- W2014450504 hasConceptScore W2014450504C111919701 @default.
- W2014450504 hasConceptScore W2014450504C111998727 @default.
- W2014450504 hasConceptScore W2014450504C121120078 @default.
- W2014450504 hasConceptScore W2014450504C139066938 @default.
- W2014450504 hasConceptScore W2014450504C161790260 @default.
- W2014450504 hasConceptScore W2014450504C178790620 @default.
- W2014450504 hasConceptScore W2014450504C185592680 @default.
- W2014450504 hasConceptScore W2014450504C188027245 @default.
- W2014450504 hasConceptScore W2014450504C191015642 @default.
- W2014450504 hasConceptScore W2014450504C2776568683 @default.
- W2014450504 hasConceptScore W2014450504C2777935641 @default.
- W2014450504 hasConceptScore W2014450504C34594497 @default.
- W2014450504 hasConceptScore W2014450504C41008148 @default.
- W2014450504 hasConceptScore W2014450504C44228677 @default.
- W2014450504 hasConceptScore W2014450504C521977710 @default.
- W2014450504 hasConceptScore W2014450504C54175244 @default.