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- W2014451617 abstract "Abstract The solubilities of NaI and KI and solid phase composition existing in equilibrium with saturated salt solution in water-n-propyl alcohol system at 25°C have been determined. It was found that the solubility curve of NaI as a function of alcohol content is divided into two areas oppositely to KI, where the observed dependence is monotonic. The changes of the plot of the solubility curves reflect the changes in the solid phase compositions. It was concluded that NaI was preferentially hydrated in almost the whole range of water-n-propyl alcohol mixture. The dependencies of the logarithm of solubility on the reciprocal of electric permittivity of mixed solvent exhibit two linear sections with intersection points ca. 60–65 mol% of alcohol. The influence of the electric permittivity on solubility is more distinct in the case of KI. The precipitating constant of n-propyl alcohol is for KI ten times higher than for NaI. So, n-propyl alcohol is a good precipitator for KI and worse for NaI in water-n-propyl alcohol mixture." @default.
- W2014451617 created "2016-06-24" @default.
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- W2014451617 date "1994-01-01" @default.
- W2014451617 modified "2023-10-06" @default.
- W2014451617 title "Solubilities of Sodium and Potassium Iodides in Water-<i>n</i>-Propyl Alcohol Mixtures at 25°C" @default.
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- W2014451617 doi "https://doi.org/10.1080/00319109408029500" @default.
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