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- W2014470769 abstract "Abstract Ligand exchange reactions are carried out exclusively at the unique iron site of a subsite‐differentiated cyclotriveratrylene [4Fe‐4S] cluster complex. The effect of a variety of thiolate, phenolate, bidentate, and bridging ligands on the redox potential of the subsite‐differentiated [4Fe‐4S] cluster complex is studied and compared with the effects of such ligands on an [Fe 4 S 4 C 14 ] 2 ‐ cluster. The redox potential can be modulated within the range of −1.60 to −1.80 V (vs. Fc 0/+ ) by varying the ligand. The introduction of an electron releasing substituent shifts the redox potential to more negative values, whereas an electron withdrawing substituent has the opposite effect. A linear relationship exists between the number of substituted sites and the reduction potential of the cluster." @default.
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- W2014470769 date "1997-08-01" @default.
- W2014470769 modified "2023-10-07" @default.
- W2014470769 title "Subsite‐Specific Reactions of a Cyclotriveratrylene [4Fe‐4S] Cluster Complex" @default.
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- W2014470769 doi "https://doi.org/10.1002/cber.19971300819" @default.
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