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- W2014486054 abstract "The relative stabilities of two fluorous analogs, diisopropyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silyl and diisopropyl-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadeca-fluoroundecyl)silyl [C(8)F(17)(CH(2))(n)Si(i-Pr)(2), where n = 2 or 3], of the standard triisopropylsilyl (TIPS) group are compared in the setting of alcohol protection. The fluorous silyl groups can be installed under standard conditions in comparable yields to the TIPS group, but the derived fluorous silyl ethers are more labile than TIPS ethers towards cleavage by both acids and fluoride." @default.
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- W2014486054 date "2009-05-01" @default.
- W2014486054 modified "2023-10-16" @default.
- W2014486054 title "Comparison of the Relative Reactivities of the Triisopropylsilyl Group With Two Fluorous Analogs" @default.
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- W2014486054 doi "https://doi.org/10.1002/adsc.200900061" @default.
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