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• W2014509546 abstract "A highly diastereoselective 1,4-addition involving Davies' lithium amide is employed as the key reaction to prepare, in five steps from ethyl acetoacetate, an enantiomerically pure keto protected β,β′-ketoaminoester. This latter was reacted with aldehydes in an intramolecular Mannich process and furnished a direct and stereoselective access to substituted homopipecolates. The validity of this approach was achieved through a new formal asymmetric synthesis of alkaloid (+)-Calvine." @default.
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• W2014509546 date "2004-05-01" @default.
• W2014509546 modified "2023-09-25" @default.
• W2014509546 title "A β,β′-ketoaminoester as a valuable tool for the asymmetric construction of substituted homopipecolic esters: application to a formal synthesis of (+)-Calvine" @default.
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• W2014509546 doi "https://doi.org/10.1016/j.tetasy.2004.04.008" @default.
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