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- W2014515900 abstract "The acid dissociation constants of a wide range of acids in water+acetone mixtures have been combined with values for the free energy of transfer of the proton. ΔG0t(H+ to calculate values for the free energy of transfer of ions which derive only from the charge on the ion. ΔG0t(i)c. As the values of ΔG0t(H+) have been revised, revised values for the total free energies of transfer of cations and anions, ΔG0t(M+) and ΔGot(X-), are given. New data for ΔGot(MXn) is also split into values for ΔG0t(Mn+) (where n=1 and 2) and ΔG0t(X−). These free energies of transfer, both total and those deriving from the charge alone, are compared with similar free energies in other mixtures water+co-solvent. Values for ΔGot(i)c do not conform to a Born-type relationship and show the importance of structural effects in the solvent even when only the transfer of the charge is involved." @default.
- W2014515900 created "2016-06-24" @default.
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- W2014515900 date "1982-02-01" @default.
- W2014515900 modified "2023-09-23" @default.
- W2014515900 title "Ionic solvation in water + co-solvent mixtures. Part 8. Total free energies of transfer and free energies of transfer with the “neutral” component removed of single ions from water into water + acetone" @default.
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- W2014515900 doi "https://doi.org/10.1016/0040-6031(82)80007-5" @default.
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