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- W2014528003 abstract "A study of the greatest Newtonian viscosity η Ng and the dipole relaxation polarization of concentrated solutions of polymethylmethacrylate (PMMA) in a good solvent, toluene, and in a poor solvent, dihexyl oxalate, has made it possible to calculate the relaxation times and free energies of activation for dipole polarization and viscous flow. It has been shown that the values of the relaxation times for dipole polarization τ, η Ng and the free energies of activation ΔG v and ΔG d for the two processes are greater for PMMA solutions in the poor solvent than in the good solvent. This is evidence of a greater degree of structure-formation in the first type of solution than in the second. The interrelated changes that have been observed in τ, η Ng , ΔG v and ΔG d point to a common feature in the mechanisms for establishing dipole polarization and viscous flow in PMMA solutions." @default.
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- W2014528003 date "1973-01-01" @default.
- W2014528003 modified "2023-09-23" @default.
- W2014528003 title "Dielectric and rheological properties of solutions of polymethylmethacrylate in good and poor solvents" @default.
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- W2014528003 doi "https://doi.org/10.1016/0032-3950(73)90409-7" @default.
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