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- W2014530894 abstract "In saturated NH4Cl (ap.)-THF solution at room temperature, metallic samarium promoted reductive dimerization cyclization of gem-diactivated alkenes, reductive debromination of vic-dibromides, and reduction of sodium alkyl thiosulfates occur to afford corresponding functionalized cyclopentenes, (E)-alkenes, and disulfides, respectively in good yield. Only sub-stoichiometric quantities of samarium are employed in the former reactions and the trans- or trans,trans-form isomer is the majority product of the polysubstituted cyclopentene products." @default.
- W2014530894 created "2016-06-24" @default.
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- W2014530894 date "1999-08-01" @default.
- W2014530894 modified "2023-09-27" @default.
- W2014530894 title "Metallic samarium promoted reductive dimerization cyclization of gem-diactivated alkenes, reductive debromination of vic-dibromides, and reduction of sodium alkyl thiosulfates in aqueous media" @default.
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- W2014530894 doi "https://doi.org/10.1016/s0040-4020(99)00602-x" @default.
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