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• W2014554223 endingPage "1563" @default.
• W2014554223 startingPage "1556" @default.
• W2014554223 abstract "The reaction of Cp‘ReCl2S3 (Cp‘ = Me4EtC5) with slightly less than 2 equiv of a phosphine reagent results in the formation of [Cp‘Re(Cl)2(μ-S)]2, 2, which has been characterized by an X-ray diffraction study. Reactions of 2 with nucleophiles did not lead to monomeric derivatives of the type Cp‘ReS(Cl)2(Nuc). The reaction of Cp‘ReCl2(SC2H4S) with (Me3Si)2S resulted in the formation of three new products: Cp‘ReS(SC2H4S), 4; Cp‘Re(S3)(SC2H4S), 5; and a tetranuclear derivative, [(Cp‘Re)2(μ-S)(μ,η2-SC2H4S)(μ,η1-SC2H4S]2Cl2, 6. Complexes 4 and 6 have been characterized by X-ray diffraction studies. The electrochemical properties of the mononuclear ReS derivative, 4, are compared with those of ReO and ReNR analogues." @default.
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• W2014554223 date "2003-02-01" @default.
• W2014554223 modified "2023-09-27" @default.
• W2014554223 title "Syntheses of a Cp‘ReS Derivative and More Complex Products" @default.
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• W2014554223 doi "https://doi.org/10.1021/ic0206241" @default.
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