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- W2014564986 abstract "The photodissociation of HI in clusters of the type ${mathrm{Xe}}_{mathit{N}}$HI is studied theoretically to explore the possible occurrence and dynamics of the cage effect in small clusters (from N=1 to 12). The method used describes the H atom quantum mechanically, the heavy atoms classically. It is found that a cage effect, corresponding to transient vibrations of the H between heavy atoms, exists for all clusters, including XeHI. For N5 these resonances are short lived and contribute little. For N>5 the resonances are long lived and dominate the process. Steric and structural factors cause this behavior." @default.
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- W2014564986 date "1990-03-19" @default.
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- W2014564986 title "Solvation effects on chemical reaction dynamics in clusters: Photodissociation of HI in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Xe</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=italic>N</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>HI" @default.
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- W2014564986 doi "https://doi.org/10.1103/physrevlett.64.1453" @default.
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