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- W2014568401 abstract "High precision 14N NMR measurements of solvent induced nitrogen shielding variations in both the NR2 and cyano moieties of cyanamide and of N,N-dimethylcyanamide are reported. The solvent induced shielding changes are much larger for the cyano, than for the NR2 groups. The NMe2 group has a nitrogen shielding which is almost invariant to choice of solvent. Solvent effects on the cyano groups of the compounds studied closely match those observed for simple alkyl cyanides. Overall analysis of the nitrogen shielding data favours a highly non-planar geometry for the compounds studied and no significant π electron conjugation between the NR2 and the cyano groups." @default.
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- W2014568401 date "1996-06-01" @default.
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- W2014568401 title "Solvent effects on the nitrogen NMR shieldings of cyanamide and N,N-dimethyl cyanamide" @default.
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- W2014568401 doi "https://doi.org/10.1016/0022-2860(95)09205-6" @default.
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