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- W2014583282 abstract "Ziel und Ergebnis der Untersuchung ist die Synthese der relativ unbeständigen phosphororganischen Thiocyanate vom Typ R2P(X)SCN (1,12: × = O; 8: × = S) und deren Umlagerung in die thermodynamisch stabileren Isothiocyanate R2P(X)NCS (3, 24: × = O, 6: × = S). Stereochemische Untersuchungen an cyclischen diastereomeren Modellen (26→17) führen zu dem Ergebnis, daß die Umlagerung Thiocyanat → Isothiocyanat durch nucleophile Partner, z. B. SCN⊖, über ein pentakoordiniertes Zwischenprodukt oder einem entsprechenden Übergangszustand autokatalysiert wird. Synthesis, Chemistry and Stereochemistry of Phosphororganic Thiocyanates and Isothiocyanates Rearrangement of Thio- into Isothiocyanates The aim and result of the investigation is the synthesis of the relatively unstable organic phosphorus thiocyanates of the type R2P(X)SCN (1,12; × = O; 8: × = S) and their tranformation into the thermodynamically more stable isothiocyanates R2P(X)NCS (3, 24: × = O; 6: × = S). Stereochemical studies of cyclic diastereomeric (26 → 17) have shown that the conversion thiocyanate → isothiocyanate is autocatalyzed by nucleophilic partners, e. g. SCN⊖, via a pentacoordinated intermediate or a corresponding transition state." @default.
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- W2014583282 date "1977-08-15" @default.
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- W2014583282 title "Synthese, Chemie und Stereochemie phosphororganischer Thiocyanate und Isothiocyanate Umlagerung der Thio- in die Isothiocyanate" @default.
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- W2014583282 doi "https://doi.org/10.1002/jlac.197719770606" @default.
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